Mesoporous Silica-Supported Amidozirconium-Catalyzed Carbonyl Hydroboration
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چکیده
منابع مشابه
Mesoporous Silica-Supported Amidozirconium-Catalyzed Carbonyl Hydroboration
The hydroboration of aldehydes and ketones using a silica-supported zirconium catalyst is reported. Reaction of Zr(NMe2)4 and mesoporous silica nanoparticles (MSN) provides the catalytic material Zr(NMe2)n@MSN. Exhaustive characterization of Zr(NMe2)n@MSN with solid-state (SS)NMR and infrared spectroscopy, as well as through reactivity studies, suggests its surface structure is primarily ≡SiOZr...
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ژورنال
عنوان ژورنال: ACS Catalysis
سال: 2015
ISSN: 2155-5435,2155-5435
DOI: 10.1021/acscatal.5b01671